Preparation of New Azo-polyesters containing Chalcone Moiety in the main chain

Authors

  • Laila S. Diab Chemistry Department, Faculty of Science, Misurata University, Libya
  • Tareg M. Elsunaki Chemistry Department, Faculty of Science, Misurata University, Libya

Keywords:

azopolyester, interfacial, Interfacial polycondensation, chalcone

Abstract

A series of four azopolyesters were synthesized by the interfacial Polycondensation technique of a chalcone diphenols; (E)-1،3-bis(4-hydroxyphenyl)prop-2-en-1-one I or(E)-3-(4-hydroxy-3-methoxyphenyl)-1(4hydroxyphenyl)prop-2-en-1-one II with diacid chlorides namely 3,3'-Azo dibenzoyl chloride III and 4,4'-Azo dibenzoyl chloride IV. Initially, the two chalcone moieties I, II were prepared by reacting two equivalents of 4-hydroxy benzylidene or 4-hydroxy-3-methoxy benzaldehyde with one equivalent of 4-Hydroxy acetophenone in the presence of a catalytic amount of concentrated HCl and EtOH as a solvent at reflux. The resulting azopolyesters were characterized by elemental analyses and IR spectroscopy.

References

Asiri, A. M. and Salman Khan, A. Molecules 2011, 16, 523.

Rajat Ghosh, Abhijit Das. World Journal of Pharmacy and Pharmaceutical Sciences 2014, 3, 578.

Rahman, M. A. Chemical Sciences Journal 2011, 29, 1.

Budakoti, A.; Bhat, A. R. and Azam, A. European Journal of Medicinal Chemistry 2009, 44, 1317.

Dave, S. S. and Rahatgaonkar, A. M. Arabian Journal of Chemistry 2011, 30, 1.

Mizuno, C. S.; Paul, S.; Suh, N. and Rimando, A. M. Bioorganic & Medicinal Chemistry Letters 2010, 20, 7385.

Beyhan, N.; Kaymakcioglu, B. K.; Gumru, S. and Aricioglu, F. Arabian Journal of Chemistry 2013, 30, 1.

Marvel, C. S.; Young, C. H. J. Am. Chem. Soc. 1951, 73, 1066.

Podkoscielny, W. and Rudz, W. Eur. Polym. J. 1993, 29, 1115.

Armarego, W.L. Purification of laboratory chemicals. Butterworth. Heinemann, 2017, 476.

Vogel, A. I. Text Book of Practical Organic Chemistry. 4th Ed., Longman, London and New York, 1984, 610.

Jasmine, F. S.; Jonthan, D. R. and Roopsingh, D., A Study on the Synthesis and Biocidal efficacy of certain random copolyesters containing Chalcone moiety in the main chain. J. Chem. Pharm. Res. 2014, 6 (3), 1155.

Woo Duck, S. b.; Young Bae, R. c.; Marcus, J. C.; Chan Woo, L. e.; Hyung Won, R. a.; Ki Chang, J. b. and Ki Hun, P. A. European Journal of Medicinal Chemistry 2010, 45, 2010.

Sathya, S.; Reuben, J. D.; Jasmime F. S.; Roopsingh, D. and Usha, G. J. Opt. Soc. Ind. 2016, doi: 10.1007/s12596-016-0360-3.

Tomlinson, M. N. J. Chem. Sco. 1946, 753.

Al-Sunoki, T. M. Chem. Dept., Fac. Sci., Nasser. Univ., Misrata, Libya 1999.

Tareg M. E.; Ghaith S. A. and Hana M. A. ARPN Journal of Science and Technology 2017, 7, 47.

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Published

2023-06-15

How to Cite

Diab, L. S., & Elsunaki, T. M. (2023). Preparation of New Azo-polyesters containing Chalcone Moiety in the main chain. Journal of Academic Research, 26, 1–4. Retrieved from https://lam-journal.ly/index.php/jar/article/view/533

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Section

العلوم الهندسية والتطبيقية